Time-varying diffusion characteristics of different gases in coal particles

Long Qingming, Hu Qiantinga, Cheng Bo

Abstract:

Based on the analytical solution of gas diffusion in spherical coal particles with a constant diffusion coef-ficient, a calculation method of time-varying diffusion coefficient is proposed by constructing objectivefunction. The time-varying diffusion behavior of methane, nitrogen and carbon dioxide in the coal parti-cles was studied. The results show that with the increase of diffusion time, the diffusion coefficients of methane, nitrogen and carbon dioxide gas in the coal particles exhibit an attenuation characteristic, eventually approaching a limit value individually. The diffusion coefficient of carbon dioxide is larger than methane, and the diffusion coefficient of nitrogen is smallest. Significant phenomenon of limited diffusion was observed for coal of strong adsorption capability. Through the analysis of the diffusion coefficient of gases at different diffusion time, a mathematical model describing the time-varying diffusion characteristic of gases is obtained. The implementation of mixed gases to replace coal bed methane has a very important practical significance.

Keywords:Coal,Coalbed methane (CBM),Adsorption , Diffusion , Objective function

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Time-varying diffusion characteristics of different gases in coal particles